Publication detail

Evaluation of applicability of indirect photometric detection for chiral separations of selected carboxylic acids in dairy products

DVOŘÁK, M. VESPALCOVÁ, M.

Original Title

Evaluation of applicability of indirect photometric detection for chiral separations of selected carboxylic acids in dairy products

English Title

Evaluation of applicability of indirect photometric detection for chiral separations of selected carboxylic acids in dairy products

Type

conference paper

Language

Czech

Original Abstract

This work is check possibility application indirect photometric detection for enantiomers separation lactic acids and beta-hydroxybutyric acid with capillary electrophoresis. As chiral selector is used vankomycin. Verified his ability partial separation lactic acid on antipode with using picric acid as vizualition anion in background electrolyte. Used was coated capillary. Application indirect photometric detection succeed. Chiral separation beta-hydroxybutyric acid wasn't successful. They are selection suitable vizualization anions for indirect photometric detection. Are measured their electrophoretic and spectrophotometric characteristics, for determination compatibility use in capillary electrophoresis in relation with indirect photometric detection. From measured and searched characteristic was choice visualizations anions for next experimentation. According to ascertained and measured feature reflect be optimal eosine soluble in alcohol and bromophenol blue.

English abstract

This work is check possibility application indirect photometric detection for enantiomers separation lactic acids and beta-hydroxybutyric acid with capillary electrophoresis. As chiral selector is used vankomycin. Verified his ability partial separation lactic acid on antipode with using picric acid as vizualition anion in background electrolyte. Used was coated capillary. Application indirect photometric detection succeed. Chiral separation beta-hydroxybutyric acid wasn't successful. They are selection suitable vizualization anions for indirect photometric detection. Are measured their electrophoretic and spectrophotometric characteristics, for determination compatibility use in capillary electrophoresis in relation with indirect photometric detection. From measured and searched characteristic was choice visualizations anions for next experimentation. According to ascertained and measured feature reflect be optimal eosine soluble in alcohol and bromophenol blue.

Keywords

Capillary electrophoresis, chiral separation, lactic acid,

Authors

DVOŘÁK, M.; VESPALCOVÁ, M.

Released

3. 12. 2009

Publisher

Vysoké učení technické v Brně, Fakulta chemická, Purkyňova 464/118, 612 00 Brno

Location

Vysoké učení technické v Brně, Fakulta chemická, Purkyňova 464/118, 612 00 Brno

ISBN

978-80-214-3555-1

Book

STUDENTSKÁ ODBORNÁ KONFERENCE CHEMIE A SPOLEČNOST 2009 Sborník příspěvků

Edition

1

Edition number

1

Pages from

54

Pages to

55

Pages count

2

BibTex

@inproceedings{BUT65944,
  author="Miloš {Dvořák} and Milena {Vespalcová}",
  title="Evaluation of applicability of indirect photometric detection for chiral separations of selected carboxylic acids in dairy products",
  booktitle="STUDENTSKÁ ODBORNÁ KONFERENCE CHEMIE A SPOLEČNOST 2009 Sborník příspěvků",
  year="2009",
  series="1",
  number="1",
  pages="54--55",
  publisher="Vysoké učení technické v Brně, Fakulta chemická, Purkyňova 464/118, 612 00 Brno",
  address="Vysoké učení technické v Brně, Fakulta chemická, Purkyňova 464/118, 612 00 Brno",
  isbn="978-80-214-3555-1"
}