Publication detail
The comparison of chiral separations of boron cluster anoins and organic anions with cyclodextrins
HORÁKOVÁ, H. ČÁSLAVSKÝ, J. VESPALEC, R.
Original Title
The comparison of chiral separations of boron cluster anoins and organic anions with cyclodextrins
Type
conference paper
Language
English
Original Abstract
Our electrophoretic chiral separation study of boron cluster compounds shows that sterically delocalized electrons meaningfully modify intermolecular interactions of boron cluster species with cyclodextrins as well as speed these interactions. Observed differences are pronounced enough that the modifying effect chemical clusters containing boron atoms ha ve to be considered determining or at least dominating for these interactions. But, the modifying influence of clusters is not restricted to intermolecular interactions facilitating chiral separations. It shows the markedly different influence of cations of weak organic bases on broadening of zones of boron cluster anions and organic anions detected by indirect photometry
Keywords
capillary electrophoresis, boron cluster compounds, chiral separations
Authors
HORÁKOVÁ, H.; ČÁSLAVSKÝ, J.; VESPALEC, R.
RIV year
2009
Released
26. 8. 2009
Publisher
Nordic Separation Science Society
Location
Tallin
ISBN
978-9985-59-930-3
Book
5th Conference by Nordic Separation Science Society: Abstract Book and Program
Edition
1
Edition number
1
Pages from
45
Pages to
45
Pages count
1
BibTex
@inproceedings{BUT29680,
author="Hana {Horáková} and Josef {Čáslavský} and Radim {Vespalec}",
title="The comparison of chiral separations of boron cluster anoins and organic anions with cyclodextrins",
booktitle="5th Conference by Nordic Separation Science Society: Abstract Book and Program",
year="2009",
series="1",
number="1",
pages="45--45",
publisher="Nordic Separation Science Society",
address="Tallin",
isbn="978-9985-59-930-3"
}