Detail publikace

The comparison of chiral separations of boron cluster anoins and organic anions with cyclodextrins

HORÁKOVÁ, H. ČÁSLAVSKÝ, J. VESPALEC, R.

Originální název

Typ

článek ve sborníku ve WoS nebo Scopus

Jazyk

angličtina

Originální abstrakt

Our electrophoretic chiral separation study of boron cluster compounds shows that sterically delocalized electrons meaningfully modify intermolecular interactions of boron cluster species with cyclodextrins as well as speed these interactions. Observed differences are pronounced enough that the modifying effect chemical clusters containing boron atoms ha ve to be considered determining or at least dominating for these interactions. But, the modifying influence of clusters is not restricted to intermolecular interactions facilitating chiral separations. It shows the markedly different influence of cations of weak organic bases on broadening of zones of boron cluster anions and organic anions detected by indirect photometry

Klíčová slova

capillary electrophoresis, boron cluster compounds, chiral separations

Autoři

HORÁKOVÁ, H.; ČÁSLAVSKÝ, J.; VESPALEC, R.

Rok RIV

2009

Vydáno

26. 8. 2009

Nakladatel

Nordic Separation Science Society

Místo

Tallin

ISBN

978-9985-59-930-3

Kniha

5th Conference by Nordic Separation Science Society: Abstract Book and Program

Edice

Číslo edice

Strany od

Strany do

Strany počet

BibTex

@inproceedings{BUT29680,
  author="Hana {Horáková} and Josef {Čáslavský} and Radim {Vespalec}",
  title="The comparison of chiral separations of boron cluster anoins and organic anions with cyclodextrins",
  booktitle="5th Conference by Nordic Separation Science Society: Abstract Book and Program",
  year="2009",
  series="1",
  number="1",
  pages="45--45",
  publisher="Nordic Separation Science Society",
  address="Tallin",
  isbn="978-9985-59-930-3"
}