Description in English
It is generally accepted that the glass fibre reinforced polymer composites are the most viable candidates for replacing structural steel and other traditional materials in engineering applications. Thin boundary layers (interphases) between the fibre anthe polymer matrix are the most decisive with respect to the performance of both general use and high-tech fibrous composite material. Silane surface treatments of the glass fibres are commonly used in industrial processes to improve the stress transmission from the matrix into the fibre. However, the formed siloxane bonds are hydrolytically unstable, which results in worsening of mechanical properties of the composite in the presence of water and, eventually, in failure of the material. Therefore, thesilane layer should be replaced with a hydrolytically stable interphase. Thin films of plasma polymers seem to be the most promising candidates to fulfill this condition. The goal of this project is to understand a background of the

GA104/00/0708

Czech

Čech Vladimír, prof. RNDr., Ph.D. - principal person responsible

Faculty of Chemistry
- responsible department (1.1.2001 - not assigned)
Faculty of Chemistry
- beneficiary (1.1.2001 - not assigned)

SVĚRÁK, T. Fine mineral coated fillers comminution process control. In CD Proceedings of the JMP conference Comminution 04. PERTH,AUSTRALIA: Journal of Mineral Processing (U.K.), 2004. p. P01-01 (P01-13 p.)
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SVĚRÁK, T. A study on linear shape of an industrial-scale tube mill for cement clinker. In Proceedings of XX.International congress CHISA 2004. Praha: 2004. p. 174-174. ISBN: 80-86059-40-5.
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SVĚRÁK, T.; WICHTERLE, K.; CLEMENSOVÁ, G. Mechanické sítování aglomerovaného materiálu. jubilejní 50. národní konference s mezinárodní účastí CHISA 03, Srní 2003. Praha: 2003. s. C57 (C57 s.)ISBN: 80-86059-36-7.
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ČECH, V., PŘIKRYL, R. Měření adheze tenkých polymerních vrstev. Projekty FRVŠ. Brno: MŠMT ČR, 2001.
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SVĚRÁK, T.; GACHOVÁ, L.; MALYSZ, K. Calcium hydrate grinding as the part of the nanostructure process technology. Chemické listy, 2002, vol. 96, no. Symp, p. 218-222. ISSN: 0009-2770.
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ČECH, V.; PŘIKRYL, R.; BÁLKOVÁ, R.; VANĚK, J.; GRYCOVÁ, A. The influence of surface modifications of glass on glass fiber/polyester interphase properties. Journal of Adhesion Science and Technology, 2003, vol. 10, no. 17, p. 1299 ( p.)ISSN: 0169-4243.
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BÁLKOVÁ, R.; ZEMEK, J.; ČECH, V.; VANĚK, J.; PŘIKRYL, R. XPS study of siloxane plasma polymer films. Surface and Coatings Technology, 2003, vol. 174-175, no. 174-175, p. 1159 ( p.)ISSN: 0257-8972.
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PŘIKRYL, R.; ČECH, V.; BÁLKOVÁ, R.; VANĚK, J. Functional interlayers in multiphase materials. Surface and Coatings Technology, 2003, vol. 173-174, no. 173-174, p. 858-863. ISSN: 0257-8972.
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PŘIKRYL, R., SALYK, O., VANĚK, J., STUDÝNKA, J., ČECH, V. Surface processing of continuously moving fiber bundle using new helical coupled plasma system. Czechoslovak Journal of Physics, 2002, vol. 52, no. 6, p. 816-824. ISSN: 0011-4626.
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BÁLKOVÁ, R.; PŘIKRYL, R.; BUREŠOVÁ, A.; VANĚK, J.; ČECH, V. Plasma polymerized film of vinyltriethoxysilane as adhesion interlayer between glass fiber and polyester resin. Czechoslovak Journal of Physics, 2002, vol. 52, no. 6, p. 807 ( p.)ISSN: 0011-4626.
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BÁLKOVÁ, R.; BUREŠOVÁ, A.; PŘIKRYL, R.; VANĚK, J.; SMRTKA, O.; ČECH, V. Adhesion Measurement By Microbond Technique. Chemické listy, 2002, vol. 2003, no. 96, p. 250 ( p.)ISSN: 0009-2770.
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BUREŠOVÁ, A.; ČECH, V.; BÁLKOVÁ, R.; PŘIKRYL, R.; VANĚK, J. Influence of Fiber Surface Treatment on Interfacial Adhesion in Glass Fiber/Polyester system. Chemické listy, 2002, vol. 2002, no. 96, p. 550 ( p.)ISSN: 0009-2770.
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VANĚK, J.; BUREŠOVÁ, A.; PŘIKRYL, R.; STUDÝNKA, J.; ČECH, V. Thin films of organosilicon monomers prepared by plasma polymerization and wet chemical process. Chemické listy, 2002, vol. 2002, no. 96, p. 225 ( p.)ISSN: 0009-2770.
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PŘIKRYL, R.; SALYK, O.; VANĚK, J.; STUDÝNKA, J.; ČECH, V. RF Plasma System for Continuous Surface Treatment and Modification of Fiber Bundles. Chemické listy, 2002, vol. 2002, no. 96, p. 250 ( p.)ISSN: 0009-2770.
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ČECH, V. Determination of Density of Localized States in a-Si:H from the Time Relaxation of SCL Conductivity. physica status solidi, 2001, vol. 187, no. 2, p. 487 ( p.)ISSN: 0031-8965.
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ČECH, V. Analysis of Annealed Thin Polymer Films Prepared from Dichloro(methyl)phenylsilane by Plasma Polymerization. Journal of Applied Polymer Sciences, 2001, vol. 82, no. 9, p. 2106 ( p.)ISSN: 0021-8995.
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BUREŠOVÁ, A., VANĚK, J., ČECH, V., PŘIKRYL, R. COMPARISON OF ADHESIVE ORGANOSILICON FILMS PREPARED BY DIFFERENT TECHNOLOGIES. In IV. Seminář Pokroky v anorganické chemii. MU Brno: Vydavatelství MU,Brno-Kraví Hora, 2002. p. 29 ( p.)ISBN: 80-210-2951-X.
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VANĚK, J.; BÁLKOVÁ, R.; ČECH, V.; BUREŠOVÁ, A.; PŘIKRYL, R. RF-Plasma technology for thin films preparation from VTEO-monomer. In Week of doctoral students 2002. Praha: MATFYZPRESS, 2002. p. 583 ( p.)ISBN: 80-85863-88-X.
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ČECH, V.; JONES, F.; BÁLKOVÁ, R.; GORUPPA, A.; VANĚK, J.; PŘIKRYL, R. Functional nanostructures for composite interphases. In Functional nanostructures for composite interphases. Maďarsko: Maďarsko, 2003. p. 0 ( p.)
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ČECH, V.; VANĚK, J. Low-elastic modulus plasma polymer film. In International Conference NANO'03 - Abstract booklet. Brno, ČR: FSI VUT v Brně, 2003. p. 34 ( p.)
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Responsibility: Čech Vladimír, prof. RNDr., Ph.D.