Publication detail

Epitaxial Guidance of Adamantyl-Substituted Polythiophenes by Self-Assembled Monolayers

FARKA, D. CIGÁNEK, M. VESELÝ, D. KALINA, L. KRAJČOVIČ, J.

Original Title

Type

journal article in Web of Science

Language

English

Original Abstract

The anisotropic nature of charge transport through organic materials requires high control over the self-assembly of the organic materials. This is particularly so for conductive polymers, where transport occurs mainly along the polymers' backbone. Herein, we demonstrate the use of self-assembled monolayers (SAMs) to influence the self-assembly of poly(3-adamantylmethylthiophene). We employ two different SAMs, which interact with either the adamantyl- or the thiophene-functionality, respectively, and acquire distinct topologies as compared to the unmodified Au(111) surface. We compare these results with unmodified glass and mica (muscovite) surfaces, which are typically employed in the field of optoelectronics. We prove the usefulness and applicability of epitaxial effects and adamantyl substituents for organic electronics. This presents a viable way toward improved electronic performance for the field as a whole.

Keywords

Self-assembly; adamantane; monolayers; organic electronics

Authors

FARKA, D.; CIGÁNEK, M.; VESELÝ, D.; KALINA, L.; KRAJČOVIČ, J.

Released

3. 9. 2024

Publisher

AMER CHEMICAL SOC

Location

WASHINGTON

ISBN

2470-1343

Periodical

ACS OMEGA

Year of study

Number

State

United States of America

Pages from

38733

Pages to

38742

Pages count

URL

https://pubs.acs.org/doi/full/10.1021/acsomega.4c04616

BibTex

@article{BUT189619,
  author="FARKA, D. and CIGÁNEK, M. and VESELÝ, D. and KALINA, L. and KRAJČOVIČ, J.",
  title="Epitaxial Guidance of Adamantyl-Substituted Polythiophenes by Self-Assembled Monolayers",
  journal="ACS OMEGA",
  year="2024",
  volume="9",
  number="37",
  pages="38733--38742",
  doi="10.1021/acsomega.4c04616",
  issn="2470-1343",
  url="https://pubs.acs.org/doi/full/10.1021/acsomega.4c04616"
}