Publication detail
Effect of acids and bases on electrophoretic deposition of alumina and zirconia particles in 2-propanol
CIHLÁŘ, J. DRDLÍK, D. CIHLÁŘOVÁ, Z. HADRABA, H.
Original Title
Effect of acids and bases on electrophoretic deposition of alumina and zirconia particles in 2-propanol
Type
journal article in Web of Science
Language
English
Original Abstract
The effects of acids (monochloroacetic, dichloracetic, trichloroacetic and sulfuric acids) and bases (diethanolamine, triethanolamine, piperidine) on electrophoretic mobility and electrophoretic deposition (EPD) of particles of amphoteric Al2O3 and ZrO2 in anhydrous 2-propanol were studied. It was found that the zeta-potential of Al2O3 and ZrO2 particles had in acidic and alkaline 2-propanol media opposite charge to that in aqueous medium. This phenomenon was explained by the low dissociation constants of acids and bases in 2-propanol. This enables electrosteric stabilization of Al2O3 and ZrO2 particles by acid anions and base cations. Similar electrophoretic behaviour of Al2O3 and ZrO2 particles in 2-propanolic dispersions stabilized by MCAA allowed the preparation of compact, regular layered laminates with high cohesion at the interface of layers.
Keywords
Electrophoretic deposition; Zirconia; Alumina; 2-Propanol; Electrosteric stabilization
Authors
CIHLÁŘ, J.; DRDLÍK, D.; CIHLÁŘOVÁ, Z.; HADRABA, H.
RIV year
2013
Released
2. 9. 2013
ISBN
0955-2219
Periodical
Journal of the European Ceramic Society
Year of study
33
Number
10
State
United Kingdom of Great Britain and Northern Ireland
Pages from
1885
Pages to
1892
Pages count
8
BibTex
@article{BUT99294,
author="Jaroslav {Cihlář} and Daniel {Drdlík} and Zorka {Cihlářová} and Hynek {Hadraba}",
title="Effect of acids and bases on electrophoretic deposition of alumina and zirconia particles in 2-propanol",
journal="Journal of the European Ceramic Society",
year="2013",
volume="33",
number="10",
pages="1885--1892",
doi="10.1016/j.jeurceramsoc.2013.02.017",
issn="0955-2219"
}