Publication detail

Simultaneous determination of metal traces by ICP-MS in environmental waters using SPE preconcentration on different polymeric sorbents

HOLUBOVÁ, Z. MOOS, M. SOMMER, L.

Original Title

Type

journal article - other

Language

English

Original Abstract

This paper deals with multielement profiling of microlements in the form of their isotopes 9Be, 51V, 59Co, 60Ni, 89Y, 111Cd, 208Pb, 232Th, and 238U. After their complexation by 4-(2-pyridylazo)resorcinol (PAR), 3,4-dihydroxy-9,10-dioxo-2-anthracenesulfonic acid sodium salt (ALS), 8-hydroxyquinoline-5-sulphonic acid (8-HQS), and ammonium pyrrolidinedithiocarbamate (APDC), the elements were preconcentrated and separated on Amberlite XAD-16 and Amberlite SDB-L prior to their analysis by inductively coupled plasma mass spectrometry. Various parameters such as pH, eluent type and volume, presence of surfactants and volume, and matrix effects on the retention of analytes were examined. Relative standard deviation and recovery values for four replicate determinations under optimal condition were in the range of 0.2 and 3.6 %, 59 and 98 %. The proposed method was applied to the determination of elements in lake water sample and industrial water. Recovery experiments with spiked water samples were performed.

Keywords

Solid phase extraction, Amberlite XAD-16, Amberlite SDB-L, ICP-MS, industrial waters, metal contaminants.

Authors

HOLUBOVÁ, Z.; MOOS, M.; SOMMER, L.

RIV year

2012

Released

15. 3. 2012

ISBN

0366-6352

Periodical

Chemical Papers

Year of study

Number

State

Slovak Republic

Pages from

899

Pages to

906

Pages count

BibTex

@article{BUT94803,
  author="Zuzana {Holubová} and Martin {Moos} and Lumír {Sommer}",
  title="Simultaneous determination of metal traces by ICP-MS in environmental waters using SPE preconcentration on different polymeric sorbents",
  journal="Chemical Papers",
  year="2012",
  volume="66",
  number="10",
  pages="899--906",
  issn="0366-6352"
}