Publication detail
LiYbCl4(THF)4
RICHTERA, L. JANČÍK, V. HERMANOVÁ, S. KRPOUN, K. THOMPSON-MONTERO, K.
Original Title
LiYbCl4(THF)4
Type
journal article in Web of Science
Language
English
Original Abstract
The title compound, di-[mu]-chlorido-dichlorido-1[kappa]2Cl-tetrakis(tetrahydrofuran)-1[kappa]2O,2[kappa]2O-lithiumytterbium(III), [LiYbCl4(C4H8O)4], was prepared by the reaction of YbCl3(THF)3 with LiCl in THF (THF is tetrahydrofuran). The central motif of the structure is a Yb([mu]-Cl)2Li ring. The Yb atom is hexacoordinated to four Cl atoms and two THF molecules oriented in a trans fashion. The Li atom has a tetrahedral environment and is coordinated to two Cl atoms and two THF molecules. No intermolecular interactions other than van der Waals forces were observed. Two of the THF molecules are disordered over two positions.
Keywords
metal-organic compounds, structure, single-crystal X-ray study, ytterbium
Authors
RICHTERA, L.; JANČÍK, V.; HERMANOVÁ, S.; KRPOUN, K.; THOMPSON-MONTERO, K.
RIV year
2011
Released
8. 5. 2011
Publisher
International Union of Crystallography
Location
England
ISBN
1600-5368
Periodical
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Year of study
2011
Number
E67
State
Kingdom of Denmark
Pages from
m700
Pages to
m700
Pages count
13