Publication detail
Macroscopic derivation of the kinetic mass-action law
PEKAŘ, M.
Original Title
Macroscopic derivation of the kinetic mass-action law
Type
journal article - other
Language
English
Original Abstract
Using several reaction examples with experimentally determined rate equations, traditional mass action rate equations are shown to be simplified forms of polynomial approximation to a general rate function derived by non-equilibrium thermodynamics for a mixture of fluids with linear transport properties. The mass action kinetic law is thus proved also on the macroscopic level and limited to this type of fluids.
Keywords
mass action, reaction rate, thermodynamic polynomial, thermodynamics
Authors
PEKAŘ, M.
RIV year
2010
Released
1. 1. 2010
Publisher
Springer-Verlag
ISBN
1878-5190
Periodical
Reaction Kinetics, Mechanisms and Catalysis
Year of study
99
Number
1
State
Hungary
Pages from
29
Pages to
35
Pages count
7
URL
Full text in the Digital Library
BibTex
@article{BUT48539,
author="Miloslav {Pekař}",
title="Macroscopic derivation of the kinetic mass-action law",
journal="Reaction Kinetics, Mechanisms and Catalysis",
year="2010",
volume="99",
number="1",
pages="29--35",
doi="10.1007/s11144-009-0101-6",
issn="1878-5190",
url="http://link.springer.com/10.1007/s11144-009-0101-6"
}