Publication detail

Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium

Merna, J., Cihlář, J., Kučera, M., Deffieux, A., Cramail, H.

Original Title

Type

journal article - other

Language

English

Original Abstract

Hex-1-ene polymerization in the presence of palladium and nickel diimine complexes was examined. Influence of the chain walking mechanism on the polymerization rate and polymer microstructure was investigated. The kinetic study of the most active Ni system was performed with impact on influence of monomer concentration on polymerization rate and polyolefin microstructure. Catalyst efficiency was estimated. Polyhex-1-ene microstructure was investigated in detail by 1H and 13C NMR analysis.

Keywords

Nickel catalyst, living polymerization, Kinetics, Structure, Polyolefins

Authors

Merna, J., Cihlář, J., Kučera, M., Deffieux, A., Cramail, H.

RIV year

2005

Released

1. 2. 2005

Publisher

Elsevier

ISBN

0014-3057

Periodical

European Polymer Journal

Year of study

2005

Number

State

United Kingdom of Great Britain and Northern Ireland

Pages from

303

Pages to

312

Pages count

BibTex

@article{BUT46276,
  author="Jan {Merna} and Jaroslav {Cihlář} and Miloslav {Kučera} and Alain {Deffieux} and Henri {Cramail}",
  title="Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium",
  journal="European Polymer Journal",
  year="2005",
  volume="2005",
  number="41",
  pages="303--312",
  issn="0014-3057"
}