Publication detail

Electrostatic effects in ionization equilibria: An AM1 study of reversed substituent effect in 5-fluorobicyclo[3.3.3]undecane-1-carboxylic acid.

Friedl, Z., Böhm, S.

Original Title

Electrostatic effects in ionization equilibria: An AM1 study of reversed substituent effect in 5-fluorobicyclo[3.3.3]undecane-1-carboxylic acid.

Type

journal article - other

Language

English

Original Abstract

Relative proton transfer enthalpies of sp and ap conformers of 5-fluorobicyclo[3.3.3]undecane-1-carboxylic acid were calculated by means of AM1 method. The reversed substituent effect was observed but overestimated due to Baeyer strain.

Keywords

reversed substituent effect, AM1

Authors

Friedl, Z., Böhm, S.

RIV year

1994

Released

12. 5. 1994

Publisher

ČSCH

Location

Praha

ISBN

0010-0765

Periodical

Collection of Czechoslovak Chemical Communication

Year of study

59

Number

6

State

Czech Republic

Pages from

1467

Pages to

1471

Pages count

5

BibTex

@article{BUT37908,
  author="Zdeněk {Friedl} and Stanislav {Böhm}",
  title="Electrostatic effects in ionization equilibria: An AM1 study of reversed substituent effect in 5-fluorobicyclo[3.3.3]undecane-1-carboxylic acid.",
  journal="Collection of Czechoslovak Chemical Communication",
  year="1994",
  volume="59",
  number="6",
  pages="5",
  issn="0010-0765"
}