Publication detail
alfa-olefin polymerization initiated by nickel catalysts:A mechanistic investigations by means of kinetic and UV-visible spectroscopy.
Merna, J., Deffieux, A., Cramail, H.
Original Title
alfa-olefin polymerization initiated by nickel catalysts:A mechanistic investigations by means of kinetic and UV-visible spectroscopy.
Type
conference paper
Language
English
Original Abstract
Kinetic study of pent-1-ene and 4-methylpent-1ene polymerization initiated by nickel diimine catalyst was performed to examine the effect of monomer structure on the polymerization rate and the polyolefin microstructure, and correlated with chain-walking mechanism. Active species formation was investigated by UV-VIS spectroscopy.
Keywords
polyolefin, nickel catalyst, kinetics, UV-VIS, mechanism
Authors
Merna, J., Deffieux, A., Cramail, H.
RIV year
2004
Released
6. 7. 2004
Location
Paris
Pages from
CD
Pages count
2