Detail publikace

Stability and structural aspects of diketopyrrolopyrrole pigment and its N-alkyl derivatives

DAVID, J. WEITER, M. VALA, M. VYŇUCHAL, J. KUČERÍK, J.

Originální název

Typ

článek v časopise - ostatní, Jost

Jazyk

angličtina

Originální abstrakt

An unsubstituted sample, three symmetrically N-substituted samples (methyl, butyl and heptyl) and two asymmetrically N-substituted samples (butyl and heptyl) of 3,6-diphenyl-2,5-dihydro-pyrrolo[3,4-c] pyrrole-1,4-dione (DPP) were investigated using thermogravimetry and differential scanning calorimetry to reveal the influence on physical-chemical properties of different alkyl chains and symmetry of Nsubstitution. Stability tests revealed that in all cases the substitution brought significant destabilization of the structure in comparison with the unsubstituted DPP molecule. It was demonstrated that the length of the substituting alkyl chain is a crucial factor in the stability of N-alkyl derivatives; the shorter the alkyl chain was, the less stable was the derivative. Further, the symmetrical derivates were less stable than the asymmetrical ones. Unlike the unsubstituted DPP molecule, all the derivatives showed remarkable sensitivity to different cooling regimes which lead to the revealing of monotropical polymorphism in the symmetrical butyl and heptyl derivatives crystalline structure.

Klíčová slova

Diphenyl-diketo-pyrrolo-pyrroles (DPPs); Pigments; Organic electronics; Thermal stability; Thermogravimetry; Calorimetry

Autoři

DAVID, J.; WEITER, M.; VALA, M.; VYŇUCHAL, J.; KUČERÍK, J.

Rok RIV

2011

Vydáno

2. 4. 2011

Nakladatel

Elsevier

Místo

ISSN

0143-7208

Periodikum

DYES AND PIGMENTS

Ročník

Číslo

Stát

Spojené království Velké Británie a Severního Irska

Strany od

137

Strany do

143

Strany počet

BibTex

@article{BUT51019,
  author="Jan {David} and Martin {Weiter} and Martin {Vala} and Jan {Vyňuchal} and Jiří {Kučerík}",
  title="Stability and structural aspects of diketopyrrolopyrrole pigment and its N-alkyl derivatives",
  journal="DYES AND PIGMENTS",
  year="2011",
  volume="89",
  number="1",
  pages="137--143",
  issn="0143-7208"
}