Detail publikace

Tuning the Electro-Optical Properties of Mixed-Halide Trityl Radicals Bearing para-Brominated Positions through Halogen Substitution

Davide Mesto, Yasi Dai, Carlo N. Dibenedetto, Angela Punzi, Jozef Krajčovič, Marinella Striccoli, Fabrizia Negri, Davide Blasi

Originální název

Tuning the Electro-Optical Properties of Mixed-Halide Trityl Radicals Bearing para-Brominated Positions through Halogen Substitution

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

In this work, the synthesis and characterization of two new trityl radicals bearing two p-brominated positions, i. e. the 2,2 '-((perchlorophenyl)methylene)bis(1,3,5-tribromobenzene) radical and the 6,6 '-((perchlorophenyl)methylene)bis(3-bromo-1,2,4,5-tetrafluorobenzene) radical, are presented. Slightly modifying the strategy typically used for the synthesis of non-symmetric mixed-halide trityl radicals, we were able to considerably increase the reaction yield for the radical precursors. In addition, for the first time the electro-optical properties of a highly fluorinated trityl radical were studied, achieving the most blue-shifted emission for a trityl radical reported up to now. Quantum-chemical calculations carried out to supplement the experimental investigation support the electrochemical and spectroscopic data as well as rationalize the observed blue shift of the highly fluorinated species.

Klíčová slova

Doublet emitters; Fluorinated compounds; Open-shell species; Trityl radicals

Autoři

Davide Mesto, Yasi Dai, Carlo N. Dibenedetto, Angela Punzi, Jozef Krajčovič, Marinella Striccoli, Fabrizia Negri, Davide Blasi

Vydáno

4. 11. 2022

Nakladatel

WILEY-V C H VERLAG GMBH

Místo

WEINHEIM

ISSN

1434-193X

Periodikum

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Číslo

4.11.2022

Stát

Spolková republika Německo

Strany od

1

Strany do

8

Strany počet

9

URL

https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202201030

BibTex

@article{BUT180385,
  author="Jozef {Krajčovič}",
  title="Tuning the Electro-Optical Properties of Mixed-Halide Trityl Radicals Bearing para-Brominated Positions through Halogen Substitution",
  journal="EUROPEAN JOURNAL OF ORGANIC CHEMISTRY",
  year="2022",
  number="4.11.2022",
  pages="1--8",
  doi="10.1002/ejoc.202201030",
  issn="1434-193X",
  url="https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202201030"
}