Detail publikace

PREPARATION OF POLYPROPYLENE COMPOSITES BY GRAFTING MONOMER TREATED FILLER

TOMEČKOVÁ, N., KUČERA F.

Originální název

PREPARATION OF POLYPROPYLENE COMPOSITES BY GRAFTING MONOMER TREATED FILLER

Typ

konferenční sborník (ne článek)

Jazyk

angličtina

Originální abstrakt

The aim of this work is to view the efficiency of grafting of itaconic anhydride to polypropylene (PP) in the presence of fillers. Due to the polarity issue between polypropylene and commercially used fillers, the itaconic anhydride was used as a compatibilizer between PP matrix and filler. Improved adhesion positively influences mechanical properties of consequential composite. Anhydride of itaconic acid was selected as a renewable resource. Glass fibers, calcite and two types of ground wooden pulp were used as fillers. Two analytical methods were chosen to analyze the efficiency of grafting: acid-base titration and infrared spectroscopy. Assigned conversion was from 42 to 87 % for various fillers. The value of conversion was determined from peak area ratio of itaconic anhydride and polypropylene in the case of infrared spectroscopy. KOH ethanolic solution was used as a titration reagent by the acid-base titration of sample solution in hot xylene. The best efficiency of grafting show samples with calcite (61,3 – 87,5 % conversion) and mixture of pine and spruce ground wooden pulp (52,7 – 65,3% conversion)

Klíčová slova

grafting, polypropylene, itaconic anhydride

Autoři

TOMEČKOVÁ, N., KUČERA F.

Vydáno

15. 8. 2011

Nakladatel

Young Scientist Council of Polymer Institute of Slovak Academy of Science

Místo

Bratislava

ISBN

978-80-968433-9-8

Kniha

International Summer School on Polymers 2011, book of abstracts

Strany počet

125

BibTex

@proceedings{BUT89231,
  editor="Nina {Kramerová}",
  title="PREPARATION OF POLYPROPYLENE COMPOSITES BY GRAFTING MONOMER TREATED FILLER",
  year="2011",
  pages="125",
  publisher="Young Scientist Council of Polymer Institute of Slovak Academy of Science",
  address="Bratislava",
  isbn="978-80-968433-9-8"
}