Detail publikace

Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium

Merna, J., Cihlář, J., Kučera, M., Deffieux, A., Cramail, H.

Originální název

Typ

článek v časopise - ostatní, Jost

Jazyk

angličtina

Originální abstrakt

Hex-1-ene polymerization in the presence of palladium and nickel diimine complexes was examined. Influence of the chain walking mechanism on the polymerization rate and polymer microstructure was investigated. The kinetic study of the most active Ni system was performed with impact on influence of monomer concentration on polymerization rate and polyolefin microstructure. Catalyst efficiency was estimated. Polyhex-1-ene microstructure was investigated in detail by 1H and 13C NMR analysis.

Klíčová slova

Nickel catalyst, living polymerization, Kinetics, Structure, Polyolefins

Autoři

Merna, J., Cihlář, J., Kučera, M., Deffieux, A., Cramail, H.

Rok RIV

2005

Vydáno

1. 2. 2005

Nakladatel

Elsevier

ISSN

0014-3057

Periodikum

European Polymer Journal

Ročník

2005

Číslo

Stát

Spojené království Velké Británie a Severního Irska

Strany od

303

Strany do

312

Strany počet

BibTex

@article{BUT46276,
  author="Jan {Merna} and Jaroslav {Cihlář} and Miloslav {Kučera} and Alain {Deffieux} and Henri {Cramail}",
  title="Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium",
  journal="European Polymer Journal",
  year="2005",
  volume="2005",
  number="41",
  pages="303--312",
  issn="0014-3057"
}