Detail publikace

Comparison of liquid and liquid-gas phase plasma reactors for discoloration of azo dyes: Analysis of degradation products

KOZÁKOVÁ, Z. KLÍMOVÁ, E. OBRADOVIC, B M DOJCINOVIC, B P KRČMA, F. KURAICA, M M OLEJNÍČKOVÁ, Z SÝKORA, R. VÁVROVÁ, M.

Originální název

Comparison of liquid and liquid-gas phase plasma reactors for discoloration of azo dyes: Analysis of degradation products

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

Three plasma systems are used for decomposition of two organic textile dyes. The highest discoloration efficiency over 90% is reached in the water falling film DBD when maximal energy of 270 and 450kJL(-1) is applied into Reactive Yellow 125 and Direct Red 79 dye solutions, respectively. Decomposition of the dye molecules is confirmed by concentration decreases in dye chromatograms. Similar degradation products are identified in the positive diaphragm discharge and water falling film DBD. In the negative diaphragm discharge, different products are formed due to electrochemical reactions on the anode. Substitution of halogens, hydrogen addition on the azo group and the cleavage of the azo group itself are the main mechanisms contributing to the destruction of the dye molecule in the compared plasma systems.

Klíčová slova

azo textile dyes; DC discharges; dielectric barrier discharges; discoloration; HPLC-MS analyses

Autoři

KOZÁKOVÁ, Z.; KLÍMOVÁ, E.; OBRADOVIC, B M; DOJCINOVIC, B P; KRČMA, F.; KURAICA, M M; OLEJNÍČKOVÁ, Z; SÝKORA, R.; VÁVROVÁ, M.

Vydáno

4. 6. 2018

ISSN

1612-8850

Periodikum

Plasma Processes and Polymers

Ročník

15

Číslo

6

Stát

Spolková republika Německo

Strany od

1700178-1

Strany do

1700178-13

Strany počet

13

URL