Projekt - Studium elektronových procesů v molekulárních systémech pro organickou fotoniku

Zdroje financování

Grantová agentura České republiky - Standardní projekty

- plně financující (2015-01-01 - 2017-12-31)

O projektu

V rámci projektu se budeme zabývat výzkumem organických materiálů pro obnovitelné zdroje energie, jmenovitě materiálů pro fotovoltaickou konverzi solární energie. Experimentálně i teoreticky budeme u nové generace nízkomolekulárních organických polovodičů studovat elektronové procesy související s přenosem energie a náboje po optické excitaci. Velmi rychlé elektronové procesy v těchto látkách budou zkoumány pomocí femtosekundové časově rozlišené spektroskopie. Získané výsledky budou doplněny kvantově chemickými výpočty elektronových vlastností a experimentální charakterizací optických a elektrických vlastností připravených materiálů. Tyto poznatky umožní sestrojit teoretické modely fotogenerace a transportu nosičů náboje v těchto molekulárních materiálech. Na základě navržené optimalizace procesů přenosu náboje budou vytvořeny vylepšené struktury organického solárního článku.

Popis anglicky
The proposed project is motivated by intensification of research on renewable energy sources, in particular, on the photovoltaic conversion of solar energy. The project is focused on the combined experimental and theoretical study of electron processes on molecular level associated with the energy and charge transfer after optical excitation of novel generation of small molecular organic semiconductors. Ultrafast electron processes in these materials will be investigated by means of the femtosecond time-resolved spectroscopy. This approach will be combined with quantum chemical calculations of electronic properties and experimental characterizations of optical and electrical properties of prepared materials. The obtained results will be used for particularization of the theoretical models of the charge carrier photogeneration and transport in small molecular materials. Finally, the optimization of the charge transfer processes will be used for an improved structure of the organic solar cells, which will be suggested and prepared.

Klíčová slova
Fotogenerace; přenos energie; časově rozlišená spektroskopie; molekulární polovodiče; fotovoltaika

Klíčová slova anglicky
Photogeneration; energy transfer; time-resolved spectroscopy; molecular semiconductors; photovoltaics

Označení

GA15-05095S

Originální jazyk

čeština

Řešitelé

Weiter Martin, prof. Ing., Ph.D. - hlavní řešitel

Útvary

Centrum materiálového výzkumu
- odpovědné pracoviště (08.12.2017 - nezadáno)
Fakulta chemická
- příjemce (01.01.2015 - 31.12.2017)

Výsledky

KRAJČOVIČ, J.; KOVALENKO, A.; HEINRICHOVÁ, P.; VALA, M.; WEITER, M. Solid- state deep blue and UV fluorescent dyes based on para- bis(2- thienyl) phenylene. Journal of Luminescence, 2015, vol. 2015, no. 167, p. 222-226. ISSN: 0022-2313.
Detail

KRAJČOVIČ, J.; RICHTÁR, J.; KOVALENKO, A.; WEITER, M. Bio-inspired riboflavin derivatives for organic electronics and biomimetic energy storage. 4th International Winterschool on Bioelectronics, Kirchberg in Tirol, Austria. 2017.
Detail

KRAJČOVIČ, J. Molecular tuning; Powerful tool at synthesis of Smart molecules for Organic electronics. Chemistry & Life 2015 - Book of Abstacts. 2015. p. 143-144. ISBN: 978-80-214-5228- 2.
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SIDEROV, V.; GEORGIEV, G.; ZHIVKOV, I.; DOBRIKOV, G.; YORDANOV, R.; VALA, M.; WEITER, M. Measurement of organic solar cell parameters. Annual Journal of Electronics, 2015, no. 9, p. 175-177. ISSN: 1314-0078.
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STOYANOVA, D.; KITOVA, S.; DIKOVA, J.; KANDINSKA, M.; VASILEV, A.; ZHIVKOV, I.; KOVALENKO, A. The impact of active layer nanomorphology on the efficiency of organic solar cells, based on a squaraine dye as a donor. Sofia: Institute of Electronics - BAS, 2015. p. 1 (1 s.).
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Alexander Kovalenko, Darina Stoyanova, Jan Pospisil, Ivaylo Zhivkov, Ladislav Fekete, Daniela Karashanova, Irena Kratochvílová, Martin Vala and Martin Weiter. Morphology versus Vertical Phase Segregation in Solvent Annealed Small Molecule Bulk Heterojunction Organic Solar Cells. INTERNATIONAL JOURNAL OF PHOTOENERGY, 2015, vol. 2015, no. 2015, p. 1-8. ISSN: 1110-662X.
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GEORGIEVA, G.; DIMOV, D.; DOBRIKOV, G.; VALA, M.; WEITER, M.; ZHIVKOV, I. VACUUM DEPOSITED ORGANIC SOLAR CELL STRUCTURES. VEIT 2015. 2015. p. 114-115.
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GEORGIEVA, G.; DOBRIKOV, G.; HEINRICHOVÁ, P.; KARASHANOVA, D.; DIMOV, D.; VALA, M.; WEITER, M.; ZHIVKOV, I. Vacuum deposited Diphenyl-Diketo-Pyrrolopyrrolе solar cell structures. Journal of Physics: Conference Series, 2016, vol. 700, no. 1, p. 1-5. ISSN: 1742-6588.
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STOYANOVA, D.; KITOVA, S.; DIKOVA, J.;KANDINSKA, M.; VASILEV, A.; ZHIVKOV, I.; KOVALENKO, A. The impact of active layer nanomorphology on the efficiency of organic solar cells, based on a squaraine dye electron donor. Journal of Physics: Conference Series, 2016, vol. 3, no. 4, p. 1-5. ISSN: 1742-6588.
Detail

GEORGIEVA, G.; DIMOV, D.; ZHIVKOV, I.; HONOVÁ, J.; VALA, M.; WEITER, M. All-dry processed organic solar cell structures. Brno: Masarykova univerzita, 2015. p. 92-92.
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SIDEROV, V.; HEINRICHOVÁ, P.; VALA, M.; WEITER, M.; ZHIVKOV, I. Determination of electrophoretic suspension properties by optical measurements. Sofia: Bulgarian Academy of Science, 2015. p. 23-24.
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SIONOVÁ, M.; VALA, M.; KRAJČOVIČ, J.; WEITER, M. Optical and optoelectronic characterization of novel diketopyrrolopyrroles for organic electronics and photonics. In Materials Science Forum. Materials Science Forum. 2016. p. 183-188. ISBN: 978-80-214-5228-2. ISSN: 0255-5476.
Detail

HEINRICHOVÁ, P.; DZIK, P.; TKACZ, J.; VALA, M.; WEITER, M. UV-Cured TiO2 Electron Transport Layer for Printable Solar Cells. RSC Advances, 2016, no. 6, p. 66705-66711. ISSN: 2046-2069.
Detail

Alexander Kovalenko, Ivaylo Zhivkov, Patricie Heinrichová, Jan Pospíšil, Jana Honová, Martin Vala and Martin Weiter. Reducing Recombination Processes in the Inverted Solution Processed Small Molecule Solar Cells by the Inserted Fullerene Cathode. IEEE Journal of Photovoltaics, 2016, vol. 6, no. 4, p. 1051-1054. ISSN: 2156-3381.
Detail

Jana Honová, Stanislav Luňák, Martin Vala, Stanislav Střítesk ́y, Ladislav Fekete, Martin Weiter, Alexander Kovalenko. Thiophene-free diphenyl-amino-stilbene-diketo-pyrrolo-pyrrole derivatives as donors for organic bulk heterojunction solar cells. Chemical Papers, 2016, vol. 1, no. 1, p. 1-9. ISSN: 1336-9075.
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Alexander Kovalenko, Jana Honová, Martin Vala, Stanislav Luňák, Ladislav Fekete, Petra Horáková, Lenka Dokládalová, Lubomír Kubáč, and Martin Weiter. Effect of the Side Chains and Anode Material on Thermal Stability and Performance of Bulk-Heterojunction Solar Cells Using DPP(TBFu) 2 Derivatives as Donor Materials. INTERNATIONAL JOURNAL OF PHOTOENERGY, 2015, vol. 1, no. 1, p. 1-9. ISSN: 1110-662X.
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KRAJČOVIČ, J.; KOVALENKO, A.; HEINRICHOVÁ, P.; VALA, M.; WEITER, M. SYNTHESIS OF NEW ORGANIC SOLID-STATE FLUORESCENT DYES BASED ON PARA-BIS(2-THIENYL)PHENYLENE DERIVATIVES CONTAINING OF ETHYL-ADAMANTYL SIDE GROUPS. BOSS XV, 15th Belgian Organic Synthesis Symposium. Belgie: 2016.
Detail

Alexander Kovalenko , Raghvendra Singh Yadav, Jan Pospisil, Oldrich Zmeskal, Daniela Karashanova, Patricie Heinrichová, Martin Vala, Jaromir Havlica, Martin Weiter. Towards improved efficiency of bulk-heterojunction solar cells using various spinel ferrite magnetic nanoparticles. ORGANIC ELECTRONICS, 2016, vol. 39, no. 1, p. 118-126. ISSN: 1566-1199.
Detail

GEORGIEVA, G.; ZHIVKOV, I.; DIMOV, D.; DOBRIKOV, G.; D. Karashanova, A. Kirilov, F. Markova, E. Bubev, A. Georgiev, R. Yordanov. Vacuum co-deposition of organic solar cell structures. BULGARIAN CHEMICAL COMMUNICATIONS, 2016, vol. 48, no. 48, p. 213-218. ISSN: 0324-1130.
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DIMOV, D.; NEDELCHEV, L.; NAZAROVA, D.; IVANOV, D.; MATEEV, G.; BUBEV, E.; GEORGIEV, A.; YANCHEVA, D.; ZHIVKOV, I; MACHKOVA, M. Application and spectral characterization of vapour deposited 4-aminoazobenzene dyes nanosized films. BULGARIAN CHEMICAL COMMUNICATIONS, 2016, vol. G, no. 48, p. 203-207. ISSN: 0324-1130.
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GEORGIEV, A.; BUBEV, E.; DIMOV, D.; YANCHEVA, D.; ZHIVKOV, I.; KRAJČOVIČ, J.; VALA, M.; WEITER, M.; MACHKOVA, M. Synthesis, structure, spectral properties and DFT quantum chemical calculations of 4-aminoazobenzene dyes. Effect of intramolecular hydrogen bonding on photoisomerizati. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2017, no. 175, p. 76-91. ISSN: 1386-1425.
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Alexander Kovalenko, Jan Pospisil, Oldrich Zmeskal,Josef Krajcovic,Martin Weiter. Ionic origin of a negative capacitance in lead halide perovskites. Physica Status Solidi-Rapid Research Letters, 2017, vol. 1, no. 1, p. 1-5. ISSN: 1862-6254.
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Vala, M.; Koutný, J.; Kovalenko, A.; Krajčovič, J.; Heinrichová, P.; Luňák, S.; Horáková, P.; Kubáč, L.; Vyňuchal, J.; WEITER, M. DIKETOPYRROLOPYRROLES: PERSPECTIVE MATERIALS FOR ORGANIC PHOTONICS. Book of Abstracts of The 12th International Conference on Organic Electronics. Bratislava, Slovakia: Slovak University of Technology in Bratislava, 2016. ISBN: 978-80-227-4571-0.
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Vala, M.; Koutný, J.; Krajčovič, J.; Luňák, S.; WEITER, M. Diketo-pyrrolo-pyrroles: prospective materials for nonlinear optical applications. Gotteborg, Sweeden: Chalmers, 2016.
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Vala, M.; Krajčovič, J.; Kovalenko, A.; Yumusak, C.; Heinrichová, P.; Stříteský, S.; Sariciftci, N.S.; Weiter, M. Adamantyl side group containing organic semiconductors for high performance OTFTs. Organic Semiconductors Conference. London, Great Britain: Imperial College London, 2016.
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SCHMIEDOVÁ, V.; POSPÍŠIL, J.; KOVALENKO, A.; ASHCHEULOV, P.; FEKETE, L.; ČUBOŇ, T.; KOTRUSZ, P.; ZMEŠKAL, O.; WEITER, M. Physical properties investigation of reduced graphene oxide thin films prepared by material inkjet printing. Journal of Nanomaterials, 2017, no. 2017, p. 1-8. ISSN: 1687-4129.
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Alexander Kovalenko, Jan Pospisil Jozef Krajcovic Martin Weiter Antonio Guerrero, Germa Garcia-Belmonte. Interface inductive currents and carrier injection in hybrid perovskite single crystals. Applied Physics Letters, 2017, vol. 111, no. 0, p. 1-4. ISSN: 1077-3118.
Detail

KRAJČOVIČ, J.; KOVALENKO, A.; HEINRICHOVÁ, P.; STŘÍTESKÝ, S.; VALA, M.; WEITER, M. Adamantane substitutions: synthesis of high-performing, soluble and versatile organic semiconducting materials. 13th International Symposium on Functional π-Electron Systems (Fπ-13) June 04 - 09, 2017 – Hong Kong University of Science and Technology, Hong Kong, China. 2017.
Detail

HEINRICHOVÁ, P.; KOVALENKO, A.; DZIK, P.; ZHIVKOV, I.; VALA, M.; WEITER, M.; HONOVÁ, J. Development of Large Area Organic Solar Cells. Chemistry and life 2015 - Book of Abstracts. Brno: Brno University of Technology, Faculty of chemistry, 2015. p. 27-28. ISBN: 978-80-214-5228-2.
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Odpovědnost: Weiter Martin, prof. Ing., Ph.D.